Hybrid Materials @ CCME
Peking University
Welcome to the Hybrid Materials Research Group website! Our research interest is to search for new organic-inorganic hybrid materials, to understand and control their properties, and to develop photonic and quantum devices from these materials. We use a variety of crystallographic and spectroscopic techniques to study these questions, including single crystal X-ray diffraction, electrical measurement, and time- and space-resolved optical spectroscopy. Please explore our website for more details.
(58) Stereochemically Active Lone Pairs and Nonlinear Optical Properties of Two-dimensional Multilayered Tin and Germanium Iodide Perovskites
Xinyu Li; Yan Guan; Xiaotong Li*; and Yongping Fu*
Journal of the American Chemical Society, 2022, doi.org/10.1021/jacs.2c07535
(57) The Chemistry and Physics of Organic−Inorganic Hybrid Perovskite Quantum Wells
Yongping Fu*
Science China Chemistry, 2022, doi.org/10.1007/s11426-022-1389-6 (Emerging Investigator Issue)
(56) Understanding Electron–Phonon Interactions in 3D Lead Halide Perovskites from the Stereochemical Expression of 6s2 Lone Pairs
Xu Huang; Xiaotong Li; Yu Tao; Songhao Guo; Jiazhen Gu; Huilong Hong; Yige Yao; Yan Guan; Yunan Gao; Chen Li; Xujie Lü; and Yongping Fu*
Journal of the American Chemical Society, 2022, 144, 27, 12247–12260
(55) Stabilization of Metastable Halide Perovskite Lattices in the 2D Limit
Yongping Fu*;
Advanced Materials, 2022, 34, 2108556
(54) Stereochemical expression of ns2 electron pairs in metal halide perovskites
Yongping Fu*; Song Jin; and X.-Y. Zhu*;
Nature Reviews Chemistry, 2021, 5: 838–852
Our work on understanding electron-phonon interactions and lone pair effects in 3D lead halide perovskites is published at JACS. Congratulations to Xu Huang! View online
Our perspective paper entitled "Stabilization of Metastable Halide Perovskite Lattices in the 2D Limit" is published on Advanced Materials. We discuss an unprecedented stabilization of metastable perovskite lattices in the 2D limit (e.g., with a thickness down to a few unit cells) due to the dominance of surface effects. This stabilization enables new insights on the relationships between the crystal structures and optoelectronic and ferroelectric properties in halide perovskites. View online
Our review paper entitled " Stereochemical expression of ns2 electron pairs in metal halide perovskites" is published on Nature Review Chemistry. We establish a unifying structure-property relationship among chemical composition, centro-symmetry breaking, lattice anharmonicity, ferroelectricity, dielectric screening, and Rashba effect in metal halide perovskites from the perspective of stereochemical expression of ns2 electron pairs on the group IV metal cations. View online
